P. Bruice – Organic Chemistry (2016)

Автор: P. Bruice
Название книги: Organic Chemistry (2016)
Формат: PDF
Жанр: Химия
Страницы: 1340
Качество: Изначально компьютерное, E-book

Paula Bruice’s presentation in Organic Chemistry, Eighth Edition provides mixed-science majors with the conceptual foundations, chemical logic, and problem-solving skills they need to reason their way to solutions for diverse problems in synthetic organic chemistry, biochemistry, and medicine. The Eighth Edition builds a strong framework for thinking about organic chemistry by unifying principles of reactivity that students will apply throughout the course, discouraging memorization. With more applications than any other textbook, Dr. Bruice consistently relates structure and reactivity to what occurs in our own cells and reinforces the fundamental reason for all chemical reactions—electrophiles react with nucleophiles. New streamlined coverage of substitution and elimination, updated problem-solving strategies, synthesis skill-building applications and tutorials guide students throughout fundamental and complex content in both the first and second semesters of the course.
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Brief Table of Contents
Remembering General Chemistry: Electronic Structure and Bonding
Acids and Bases: Central to Understanding Organic Chemistry
Acids and Bases
An Introduction to Organic Compounds: Nomenclature, Physical Properties, and Structure
Using Molecular Models
Isomers: The Arrangement of Atoms in Space
Interconverting Structural Representations
Alkenes: Structure, Nomenclature, and an Introduction to Reactivity. Thermodynamics and Kinetics
Drawing Curved Arrows
The Reactions of Alkenes. The Stereochemistry of Addition Reactions
The Reactions of Alkynes. An Introduction to Multistep Synthesis
Delocalized Electrons: Their Effect on Stability, pK a , and the Products of a Reaction. Aromaticity and Electronic Effects: An Introduction to the Reactions of Benzene
Drawing Resonance Contributors
Substitution and Elimination Reactions of Alkyl Halides
Reactions of Alcohols, Ethers, Epoxides, Amines, and Sulfur-Containing Compounds
Organometallic Compounds
Radicals
Drawing Curved Arrows in Radical Systems
Mass Spectrometry; Infrared Spectroscopy; UV/Vis Spectroscopy
NMR Spectroscopy
Reactions of Carboxylic Acids and Carboxylic Acid Derivatives
Reactions of Aldehydes and Ketones More Reactions of Carboxylic Acid Derivatives
Reactions at the a-Carbon
Synthesis and Retrosynthetic Analysis
Reactions of Benzene and Substituted Benzenes
More About Amines. Reactions of Heterocyclic Compounds
The Organic Chemistry of Carbohydrates
Amino Acids, Peptides, and Proteins
Catalysis in Organic Reactions and in Enzymatic Reactions
The Organic Chemistry of the Coenzymes, Compounds Derived from Vitamins
The Organic Chemistry of the Metabolic Pathways
The Organic Chemistry of Lipids
The Chemistry of the Nucleic Acids
Synthetic Polymers
Pericyclic Reactions
Appendices
pK a Values
Kinetics
Summary of Methods Used to Synthesize a Particular Functional Group
Summary of Methods Employed to Form Carbon–Carbon Bonds
Spectroscopy Tables
Physical Properties of Organic Compounds
Answers to Selected Problems