S. Stahl – Liquid Phase Aerobic Oxidation Catalysis (2016)

Автор: S. Stahl
Название книги: Liquid Phase Aerobic Oxidation Catalysis
Формат: PDF
Жанр: Химия
Страницы: 429
Качество: Изначально компьютерное, E-book

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead.
As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock.
With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Radical Chain Aerobic Oxidation
Overview of Radical Chain Oxidation Chemistry
Noncatalyzed Radical Chain Oxidation: Cumene Hydroperoxide
Cyclohexane Oxidation: History of Transition from Catalyzed to Noncatalyzed
Chemistry and Mechanism of Oxidation of para-Xylene to Terephthalic Acid Using Co–Mn–Br Catalyst
Cu-Catalyzed Aerobic Oxidation: Overview and New Developments
Copper-Catalyzed Aerobic Alcohol Oxidation
Phenol Oxidations
Pd-Catalyzed Aerobic Oxidation
Pd-Catalyzed Aerobic Oxidation Reactions: Industrial Applications and New Developments
Acetaldehyde from Ethylene and Related Wacker-Type Reactions
1,4-Butanediol from 1,3-Butadiene
Mitsubishi Chemicals Liquid Phase Palladium-Catalyzed Oxidation Technology: Oxidation of Cyclohexene, Acrolein, and Methyl Acrylate to Useful Industrial Chemicals
Oxidative Carbonylation: Diphenyl Carbonate
Aerobic Oxidative Esterification of Aldehydes with Alcohols: The Evolution from Pd–Pb Intermetallic Catalysts to Au–NiO x Nanoparticle Catalysts for the Production of Methyl Methacrylate
Organocatalytic Aerobic Oxidation
Quinones in Hydrogen Peroxide Synthesis and Catalytic Aerobic Oxidation Reactions
NO x Cocatalysts for Aerobic Oxidation Reactions: Application to Alcohol Oxidation
N-Hydroxyphthalimide (NHPI)-Organocatalyzed Aerobic Oxidations: Advantages, Limits, and Industrial Perspectives
Carbon Materials as Nonmetal Catalysts for Aerobic Oxidations: The Industrial Glyphosate Process and New Developments
Biocatalytic Aerobic Oxidation
Enzyme Catalysis: Exploiting Biocatalysis and Aerobic Oxidations for High-Volume and High-Value Pharmaceutical Syntheses
Oxidative Conversion of Renewable Feedstocks
From Terephthalic Acid to 2,5-Furandicarboxylic Acid: An Industrial Perspective
Azelaic Acid from Vegetable Feedstock via Oxidative Cleavage with Ozone or Oxygen
Oxidative Conversion of Renewable Feedstock: Carbohydrate Oxidation
Aerobic Oxidation with Singlet Oxygen
Industrial Prospects for the Chemical and Photochemical Singlet Oxygenation of Organic Compounds
Reactor Concepts for Liquid Phase Aerobic Oxidation
Reactor Concepts for Aerobic Liquid Phase Oxidation: Microreactors and Tube Reactors